Suffolk County led all 62 New York counties in opiate overdose deaths in 2014, as the number of heroin- and prescription pill-related fatalities in the state reached a record high, according to a report issued Thursday by state Comptroller Thomas DiNapoli.

The latest grim Suffolk statistics add to the tally of a separate data-rich state study from April that showed the county recorded more heroin-related overdose deaths than any other in the state from 2009 to 2013.

Heroin overdose deaths reached a record high of 825 in 2014, the last year for which data was available from the Centers for Disease Control and Prevention’s National Center for Health Statistics, according to DiNapoli’s report.

The numbers statewide represent a jump of 159 deaths, or 24 percent, over 2013, and is nearly 25 times the number recorded in New York 10 years earlier, the report states. Deaths in which prescription opioids were a contributing cause totaled 1,008 statewide in 2014, nearly quadruple the number recorded in 2005, according to the report.

It’s more evidence, DiNapoli said in a prepared statement attached to the report, of the physical, financial and emotional toll exacted by an opiate epidemic across the state despite government efforts to curb abuse.

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“Heroin and prescription opioid addiction often come with disastrous consequences, tearing apart families and causing financial ruin,” DiNapoli said. “While New York state and some local governments have taken important steps to reduce heroin and opioid abuse, the costs associated with this epidemic are growing and the health, safety and prosperity of our communities are at risk.”

Nowhere is the problem more evident than in Suffolk, with Nassau not far behind, according to the comptroller’s report.

Among New York counties, Suffolk had the highest number of heroin overdose deaths in 2014, with 111, and prescription opioid deaths, with 96, the report states. Nassau recorded 58 heroin deaths and 90 prescription opioid deaths in 2014 — third highest in both categories, behind Suffolk and Brooklyn, the report found.

DiNapoli’s office compared opiate overdose death rates for all states in which data was available for the years 2005 and 2014. They found that only one state in each category — Massachusetts for heroin-related deaths, and Connecticut for prescription opioid fatalities — had higher rates of increase in overdose deaths than New York.

About 75,000 New Yorkers were estimated to have used heroin in the two-year period from 2013 through 2014, according to data compiled by the federal Substance Abuse and Mental Health Services Administration, which was cited in the report.

That figure reflects nearly 10 percent of all heroin users in the nation during that two-year span, state officials said.

Compared to national averages, New Yorkers are significantly more likely than those in other states to be admitted for treatment for heroin use or prescription opioid abuse, the report found.

“Every statistic you see, that’s a family destroyed right there,” said Ryan Fitzgerald, 24, a recovering pill and heroin addict in Bay Shore who lost two friends to fatal opiate overdoses in 2014, reacting to the report. “That’s a lot of families.”